STUDY OF SURFACE LAYERS ON PURE TITANIUM PRODUCED BY LASER GAS NITRIDING

Authors

  • J. H. Abboud Dept. of Mech. Eng, Garyounis University, Benghazi, Libya Author
  • A. F. Fidel Dept. of Mech. Eng., Omar Al-Mukhtar University, Al-Bythaa, Libya Author
  • Y. Benyounis Dept. of Industrial Eng., Garyounis University, Benghazi, Libya Author

DOI:

https://doi.org/10.66411/jer.v10i10.176

Keywords:

Laser hardening, CP Titanium, Microstructure., XRD

Abstract

Laser gas nitriding process is a widely accepted technique for modifying the surface structure and composition of titanium and titanium alloys without altering the bulk properties. In the present work, laser gas nitriding of commercial purity titanium with continuous wave 3 kW Co2 laser has been investigated experimentally. The aim is to increase the surface hardness and hence improve related properties such as wear and erosion. The processing parameters were as follow: 2.5 kW laser power, 15 mm/s specimen scanning rate, and 17 L/min nitrogen gas flow rate. Single and overlapping layers were produced and pure and diluted nitrogen gas was used. The results indicated that laser surface melting of pure titanium in nitrogen atmosphere produced unevenly distributed TiN of dendritic morphology extended to a depth of ~ 0.5mm. The volume fraction of the TiN dendrites decreased gradually with increasing depth from the surface. As a result of TiN formation, the hardness increased substantially. Diluting the nitrogen gas with argon gas was found to have a beneficial effect in decreasing cracking but decreased the resulting hardness level and the nitrided depth

References

[1] J. Polmear, "Light Alloys", Edward Arnold, London, 1981.

[2] Ani Zhercheva, W. Sha, S.Malinova, and A. Long, "Enhancing the microstructure and properties of titanium alloys through nitriding and other surface engineering methods", Surfaces and Coating Technology; 200;(2005); pp 2192-2207. DOI: https://doi.org/10.1016/j.surfcoat.2004.07.115

[3] A.D. Wilson, A. Leyland, and A. Matthews, "A comparative study of the influence of plasma treatments, PVD coatings and ion implantation on the tribological performance of Ti– 6Al–4V", Surface and Coatings Technology; 114; (1999); pp 70–80. DOI: https://doi.org/10.1016/S0257-8972(99)00024-9

[4] Y. Enomoto and K. Yamanrat: "Synthesis of titniumcarbonitride films by physical vapour deposition and their structure", Thin Solid Films, 86; (1981); pp 201-203. DOI: https://doi.org/10.1016/0040-6090(81)90163-2

[5] A.S. Gates: "Composition, structure, and wear resistance of TiAlOC coatings deposited by chemical vapor deposition"; J. Vac. Sci. Technol., A4; (1986); pp 2707-2712. DOI: https://doi.org/10.1116/1.573711

[6] S. Katayama, A. Matsunawa, A. Morimoto, S. Ishimoto and Y. Arata,”Surface hardening of titanium by laser nitriding”, ICALEO '83 LIA, Los Angeles; (1983); pp 5 DOI: https://doi.org/10.2351/1.5057471

[7] A. Walker, J. Folkes, W. M. Steen and D. R. F. West; J. surf. Eng., 1; (1985); pp 23 DOI: https://doi.org/10.1179/sur.1985.1.1.23

[8] B.L. Mordike; "Surface modification of metals", Materials Science and Technology, vol. 15; Processing of metals and alloys, VCH, R.W. Cahn, (Ed.). Berlin. 1991. pp 36.

[9] E. Santos, M.Morita, M. Shiomi, K.Osakada, and M.Takahashi; "Laser gas nitriding of Pure titanium using CW and pulsed Nd-YAG lasers"; Surface and Coating Technology; 201; (2006); pp1635-1642. DOI: https://doi.org/10.1016/j.surfcoat.2006.02.048

[10] C. Hu, H.Xin, L.M.Watson and T.N.Baker; "Analysis of the phases developed by laser nitriding of Ti-6Al-4V alloys", Acta mater vol 45; (1997); pp 4311-4322 DOI: https://doi.org/10.1016/S1359-6454(97)00076-1

[11] A.B. Kloosterman and J.Th.M. De Hosson, “Microstructural characterization of laser nitrided titanium”, Scripta Metalluigica et Matcrialia, Vol. 33, No. 4; (1995) pp. 567-573, DOI: https://doi.org/10.1016/0956-716X(95)00238-Q

[12] S. Mridha and T.N. Baker;” Effects of nitrogen gas flow rates on the microstructure and properties of laser-nitrided IMI318 titanium alloy (Ti-6A1-4V)"; Journal of Materials Processing Technology; 77; (1998); pp 115-121. DOI: https://doi.org/10.1016/S0924-0136(97)00408-1

[13] M.S. Selamat, T.N. Baker, L.M. Watson,” Study of the surface layer formed by the laser processing of Ti-6A1-4V Alloy in a dilute nitrogen environment”, J. Mater. Process Technol. 113; (2001); pp 509-515. DOI: https://doi.org/10.1016/S0924-0136(01)00595-7

[14] V. M. Weerasinghe, D.R.F. West, M. Czajlik,” Laser surface nitriding of titanium and a titanium alloy”, 1st ASM conf. on Heat Treatment and Surf. Eng., Amsterdam, 1991

[15] I. P. Nwobu, R. D. Rawlings and D. R. F. West, “Nitride formation in titanium based substrates during laser surface melting in nitrogen-argon atmospheres”, Acta mater. Vol. 47, No. 2; (1999); pp. 631-643, DOI: https://doi.org/10.1016/S1359-6454(98)00369-3

[16] S.Mridha and T.N.Baker; "Crack – free surfaces produced laser nitriding of commercial purity titanium"; Material Science and Engineering, A188; (1994); pp.229- 239. DOI: https://doi.org/10.1016/0921-5093(94)90376-X

[17] C. Hu, T.N. Baker, “The importance of preheat before laser nitriding a Ti–6Al–4Valloy”, Materials Science and Engineering A265; (1999); pp. 268–275. DOI: https://doi.org/10.1016/S0921-5093(98)01135-6

[18] J.H.Abboud, A. F.Fidel, K.Y.Benyounis; "Surface nitriding of Ti-6Al-4V alloy with a high-power CO2 laser"; Optics & Laser Technology 40; (2008); pp. 405-414 DOI: https://doi.org/10.1016/j.optlastec.2007.07.005

[19] J.L. Murray; "Phase diagrams of binary titanium alloys"; ASM International, Metals Park, OHIO, 1987.

Downloads

Published

30-09-2008

Issue

Section

Articles

How to Cite

[1]
J. H. Abboud, A. F. Fidel, and Y. Benyounis, “STUDY OF SURFACE LAYERS ON PURE TITANIUM PRODUCED BY LASER GAS NITRIDING”, JER, vol. 10, no. 10, pp. 93–104, Sep. 2008, doi: 10.66411/jer.v10i10.176.